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The second overtone of an open pipe A and a closed pipe B have the same frequencies at a given temperature. Both the pipes contain air. The ratio of fundamental frequency of A to that of B is,
Detailed Solution: Question 1
Let, v be the velocity of a wave.
Length of open pipe A be l1.
Length of closed pipe B be l2.
Formula used:
nth overtone of an open pipe fn = (n+1)f0, where for open pipe fundamental frequency f0 = v/2l
nth overtone of a closed pipe fn = (2n+1)f0, where for closed pipe fundamental frequency f0 = v/4l.
Now, solving the problem
Since, it is given that frequencies are same,
Now, the ratio of fundamental frequencies,
A rocket is fired perpendicular to the surface of the earth with a speed equal to 50% of the escape velocity from earth surface. The maximum height reached by it in terms of radius R of the earth is :
Detailed Solution: Question 2
When the body's kinetic energy approaches zero, it reaches its maximum height.
Equating maximum height and kinetic energy
The vector product of the force (F) and distance (r) from the centre of action represents
Detailed Solution: Question 3
Torque is a measure of how much a force acting on an object causes that object to rotate. The object rotates about an axis (O). The distance from O is r,
where forces acts, hence torque τ=r x F. It is a vector quantity and points from axis of rotation to the point where the force acts.
The new white belt of a long horizontal conveyor is moving with a constant speed v = 3.0 m/s. A small block of carbon is placed on the belt with zero initial velocity relative to the ground. The block will slip a bit before moving with the belt, leaving a black mark on the belt (figure). How long is that mark (in m) if the coefficient of kinetic friction between the carbon block and the belt is 0.20 and the coefficient of static friction is 0.30?
Detailed Solution: Question 4
02 = v2 – 2µkgSrel
Amongst the following, the major product of the given chemical reaction is
Detailed Solution: Question 5
Detailed Solution: Question 6
A
Diazotisation: The aromatic -NH2 group is converted into the corresponding diazonium salt by NaNO2/HCl at low temperature.
On treatment with N,N-dimethylaniline the diazonium salt undergoes an azo coupling reaction. The diazonium species behaves as an electrophile and couples at the para position of the activated dimethylaniline ring (activation by -N(CH3)2).
The -SO3H group on the diazonium-bearing ring remains intact (it is deactivating/meta-directing but does not participate in the coupling), so the major product is the para-azo product linking the two rings by -N=N-.
Therefore the major product is the azo dye with structure HO3S-Ph-N=N-Ph-N(CH3)2, which corresponds to option A.
Detailed Solution: Question 7
Which of the following statements are correct?
(A) Both LiCl and MgCl2 are soluble in ethanol.
(B) The oxides Li2O and MgO combine with excess of oxygen to give superoxide.
(C) LiF is less soluble in water than other alkali metal fluorides.
(D) Li2O is more soluble in water than other alkali metal oxides.
Choose the most appropriate answer from the options given below:
Detailed Solution: Question 8
(A) Both LiCl and MgCl2 are covalent in nature due to high polarising power of Li+ and Mg+2 ions. Hence, they are soluble in ethanol.
(A) Oxides of Li2O and MgO do not form superoxide.
(B) LiF is least soluble among all other alkali metal fluorides due to high lattice energy of LiF.
(C) Li2O is least soluble among all other alkali metal oxides.
Hence, statements (A) and (C) are correct.
Match List-I with List-II:
Choose the most appropriate answer from the options given below:
Detailed Solution: Question 9
Hence, the most appropriate option is (a).
A graph of vapour pressure and temperature for three different liquids X, Y and Z is shown below:
The following inferences are made:
(A) X has higher intermolecular interactions compared to Y.
(B) X has lower intermolecular interactions compared to Y.
(C) Z has lower intermolecular interactions compared to Y.
The correct inference(s) is/are:
Detailed Solution: Question 10
Vapour pressure of a liquid at a given temperature is inversely proportional to intermolecular forces of attraction.
In order to attain the same vapour pressure, 'X' has to be heated the least followed by 'Y' and 'Z'.
Hence, the increasing order of the strength of intermolecular forces is: X < Y < Z.
Therefore, 'X' has lower intermolecular interactions compared to 'Y' and statement (B) is correct.
The conversion of propan-1-ol to n-butylamine involves the sequential addition of reagents. The correct sequential order of reagents is
Detailed Solution: Question 11
For the Balmer series in the spectrum of H atom, the correct statements among (l) to (IV) are:
(I) As wavelength decreases, the lines in the series converge.
(II) The integer n1 is equal to 2.
(III) The lines of longest wavelength correspond to n2 = 3.
(IV) The ionisation energy of hydrogen can be calculated from wave number of these lines.
Detailed Solution: Question 12
In the Balmer series of H-atom, electronic transitions take place from higher orbits to 2nd orbit, and the longest wavelength will correspond to the transition from 3rd orbit to 2nd orbit.
∴ n1 = 2 and n2 = 3 for longest wavelength.
As wavelength decreases, the lines in the Balmer series converge. The correct statements are (I), (II) and (III).
The ionisation energy of hydrogen can be calculated from wave number of the last line of the Lyman series:
n1 = 1 and n2 = ∞
Hence, statement IV is incorrect.
The number of bridged oxygen atoms present in compound B formed from the following reactions is
Detailed Solution: Question 13
Hence, no bridged oxygen atom is present in N2O4.
Sum of number of ions in aqueous solution of CrCl3.5NH3 and CrCl3 . 4NH3.
Detailed Solution: Question 14
Find the planar species among the following species
SF2, SF4, SF6 , SO2, SO3
Detailed Solution: Question 15
Identify total number of compound (s) which are unstable at room temperature ?
Detailed Solution: Question 16
A compound is considered unstable at room temperature if it is either antiaromatic (cyclic, planar, fully conjugated with 4n π electrons) or so reactive that it cannot be isolated under normal conditions (for example, it rapidly dimerizes).
(i) Cyclobutadiene has 4 π electrons in a planar, cyclic, fully conjugated system. It is a classic antiaromatic compound and is not stable at room temperature.
(ii) The second compound is a fulvene-type structure. Although it appears conjugated, the conjugation is cross-conjugation, not continuous cyclic conjugation. Therefore, it is neither aromatic nor antiaromatic and exists at room temperature. It is considered stable for exam purposes.
(iii) Cyclopentene is a simple alkene with no special conjugation or instability. It is stable.
(iv) Cyclopentadienone has a cyclic conjugated system with 4 π electrons in the ring. It shows antiaromatic character and is highly unstable, readily undergoing dimerization. It is not isolable at room temperature.
(v) Benzene is aromatic with 6 π electrons and is very stable.
(vi) Naphthalene is also aromatic and stable at room temperature.
(vii) Borole contains 4 π electrons and is often described as antiaromatic. Borole is highly unstable due to electron deficiency at boron and antiaromatic character, and it cannot be handled as a stable compound at room temperature.
Therefore, the unstable compounds are (i), (iv), and (vii).
Final answer: 3
27 gm of Al react with excess of oxygen to give 4.95 gm of Al2O3, calculate % yield of reaction.
Detailed Solution: Question 17
The reaction between aluminum (Al) and oxygen (O₂) to form aluminum oxide (Al₂O₃) is:
4 Al + 3 O₂ → 2 Al₂O₃
Step 2: Calculate the theoretical yield of Al₂O₃We first calculate the moles of aluminum (Al) used in the reaction.
Molar mass of aluminum (Al) = 27 g/mol
Moles of Al used = 27 g / 27 g/mol = 1 mol of Al
From the stoichiometry of the reaction, 4 moles of Al produce 2 moles of Al₂O₃. Therefore:
Moles of Al₂O₃ produced = (2 / 4) × 1 mol of Al = 0.5 mol of Al₂O₃
Now, calculate the mass of Al₂O₃ produced using its molar mass:
Molar mass of Al₂O₃ = (2 × 27) + (3 × 16) = 54 + 48 = 102 g/mol
Theoretical yield of Al₂O₃ = 0.5 mol × 102 g/mol = 51 g
The actual yield of Al₂O₃ is given as 4.95 g. The formula for percentage yield is:
Percentage Yield = (Actual Yield / Theoretical Yield) × 100
Substitute the values:
Percentage Yield = (4.95 g / 51 g) × 100 ≈ 9.7%
Final Answer:The percentage yield of the reaction is approximately 9.7%.
Detailed Solution: Question 18
Putting n = 1 in P(n)
= 72 + 20 ⋅ 30 = 49 + 1 = 50 ...(i)
Which is divisible by 25 be divisible by 25 for some k ∈ N
= a multiple of 25 as P(k) is true
Hence by PMI P(n) is divisible by 25 ∀ n ∈ N
Detailed Solution: Question 19
If n = 1 ⋅ 2 ⋅ 3 ....m (m is a fixed positive integer > 2), then is equal to
Detailed Solution: Question 20
The line y = mx intersects the circle x2 + y2 − 2x − 2y = 0 and x2 + y2 + 6x − 8y = 0 at points A and B (points being other than origin). The range of m such that origin divides AB internally is
Detailed Solution: Question 21
Let C1: (x − 1)2 + (y − 1)2 = 2
C2: (x + 3)2 + (y − 4)2 = 52
Both the circle pass through the origin.
Hence, tangents at the origin (using T = 0) to C1 and C2 are x + y = 0 and 3x − 4y = 0, respectively.
The slope of the tangents are −1 and 3/4 respectively.
Thus, if −1 < m < 3/4, then origin divides AB internally.
The letters of the word COCHIN are permuted and all the permutations are arranged in an alphabetical order as in an English dictionary. The number of words that appear before the word COCHIN is
Detailed Solution: Question 22
Arrange the letter of the word COCHIN as in the order of dictionary CCHINO
Which number of words with the two C’s occupying first and second place = 4!
Number of words starting with CH, CI, CN is each
∴ Total number of ways = 4! + 4! + 4! + 4! = 96
There are 96 words before COCHIN
Detailed Solution: Question 23
Let f(x) = [2x3 – 5]; then number of points in (1, 2) where the function is discontinuous are where [.] → G.I.F.
If the foci of the ellipse and the hyperbola
coincide, then the value of b2 is:-
Detailed Solution: Question 25
Identify the foci of the hyperbola:
The hyperbola equation is x²/144 - y²/81 = 1.
Rewriting in standard form by multiplying both sides by 25: (25x²/144) - (25y²/81) = 25.
Here, a² = 144/25 and b² = 81/25.
The distance to the foci for a hyperbola is c² = a² + b²: c² = (144/25) + (81/25) = 225/25 = 9 ⇒ c = 3.
Thus, the foci of the hyperbola are at (±3, 0).
Determine the foci of the ellipse:
The ellipse equation is x²/25 + y²/25 = 1.
Since the foci coincide with those of the hyperbola, they are at (±3, 0).
For an ellipse with major axis along the x-axis, c² = a² - b², where a² = 25: 3² = 25 - b² ⇒ 9 = 25 - b² ⇒ b² = 16.
Every sentence (given below) is divided into three section marked A, B and C. Read the sentence carefully and mark the section that contains an error. If there is no error in the sentence, mark (D).
Due to carelessness, (A)/he failed (B)/in the examination. (C)/No error. (D)
Detailed Solution: Question 26
(A) Write Owing to in place of Due to in section (A). Due to is generally used after the verb. It means, caused by somebody/something.
The correct sentence will be :
"Owing to carelessness he failed in the examination."
However, modern grammarians do not object to using due to and owing to in the same sense.
Of the given four pairs, three pairs express the relationship similar to that expressed in the capitalised pair. Select that pair that is not related in this way.
OVATION : APPLAUSE :: ?
Detailed Solution: Question 27
In the given words, both are similar in meaning. Ovation means a warm reaction given by the audience when they like something. Applause means clapping by the audience as an appreciation.
The words in option C are opposites of each other. Triumph means to gain victory over something. Failure means failing to gain success.
Hence, option C is the correct answer.
If a meaningful word can be formed from APSG, by using each letter only once, then the third letter of that word is your answer. If more than one such word can be formed, your answer is 'Y' and if no such word is formed then answer is 'Z'.
Detailed Solution: Question 28
Answer: Y
Two meaningful English words that use each letter exactly once are GASP and GAPS.
Both of these are valid words, so more than one meaningful word can be formed. Therefore the correct choice is Y (option B).
n this question, the 1st and the last sentence / parts of the passage / sentence are numbered 1 and 6. The rest of the passage / sentence is split into four parts and named P, Q, R and S. These four parts are not given in their proper order. Read the sentence and find out which of the four combinations is correct. Then find the correct answer.
1. One of the greatest advances.
P. has been the invention of computers.
Q. in modern technology.
R. in industry, administration and education.
S. which are widely used.
6. and in almost every sphere of human life.
Detailed Solution: Question 29
The central theme behind the sentences is the benefits of the invention of computers. So, Q should follow 1 because it makes it clear that where has the advancement taken place.
The next one will be P, which states the advancement that has been done.
Sentence S should follow it next as it introduces both sentences R and 6 which are about the uses of computers.
Hence, QPSR is the correct sequence.
Based on the diagrammatic information given below, answer the following question.
The circle represents rich persons.
The rectangle represents surgeons.
The square represents researchers.
The triangle represents engineers.
Some of the surgeons are neither engineers nor researchers, but they are rich persons. Which section represents them?
Detailed Solution: Question 30
As per the given figure,
1, 2, 3, 4 is represented by rich persons.
3 is represented by researchers.
2, 3, 4, 5, 7, 8 is represented by surgeons.
4, 6, 7 is represented by engineers.
So, region 2 represents some surgeons who are neither engineers nor researchers.
Hence, 2 is the correct answer.
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10 tests |