i have found lumps of it walking the railroads before it was used for something i dont know what but i found a lot of it.
I don't think Sulfur is an oxidizer in this application. It is a starting fuel, igniting at a lower temperature than the charcoal.If you're looking for it naturally occurring, you're going to need to look in areas of volcanic or geothermal activity. Then you'll need to figure out a method to extract and purify it.
Alternative thinking, there are other oxidizers besides sulfur that may be easier to find and use.
You are correct, the nitrate is the oxidizer. The sulfur binds with it to lower ignition temp.I don't think Sulfur is an oxidizer in this application. It is a starting fuel, igniting at a lower temperature than the charcoal.
Nitrates and chlorates are the oxidizers.
Considering the small percentage of sulfur used in black powder, 50 lbs of sulfur would make something like 500 lbs of black powder.Justme11 got me to thinking...found this:
50# pure elemental yellow sulfur powder
http://www.amazon.com/Ground-Elemen...tone/product-reviews/B003EE8X1C?pageNumber=10
http://civilwartalk.com/threads/black-powder-without-sulfur.96740/Adjoining this part of the Works was the Sulphur Refinery, where this material was prepared from the crude stock, and made ready for the incorporating process. About one hundred and thirty tons of very impure sulphur had been received from Louisiana, for the use of the Powder Works; it had been purchased before the war by the planters for use in the making of sugar, and was bought up by the Confederate officers. The best quality of gunpowder has its sulphur chemically pure, which could be demonstrated by showing no trace of acid when powdered and boiled in water, and should entirely evaporate on a piece of glass when heated, leaving no stain. This can only be accomplished practically by distillation. The crude article was melted and poured into upright, thick wooden boxes five feet high and ten inches square at the bottom, tapering upwards; when cold the earthy matters would be found in the lower portion by subsidence, leaving about three feet apparently pure. This was broken off and placed into two kettles of suitable form and dimensions, having furnaces; the tops of these kettles were connected by a bent iron pipe to an enlarged portion, which was surrounded with water. On the application of heat the sulphur vaporized, and passing over through the pipe was condensed in the cooled portion, whence it trickled in a thick stream into a receiving vessel below; the first portions being rejected, the remainder was of a beautiful citron yellow when cold, and entirely pure.
Just like salt; if I can't make it or find it locally I add some in our supplies along with the Spectracide stump removerIt looks like finding sulfur 'naturally' will be a bigger job than making charcoal.I better stock up on some.
It looks like it is only 40 some % Sulfur.They used to sell tubs and bags of sulfer at the hardware stores. You put it on the grass to repel chiggers. As far as I know you should be able to buy it at Lowes and Home Depot.
Here ya go:
http://www.homedepot.com/s/sulfer?NCNI-5