Forbidden lines
Forbidden lines, in astronomical spectroscopy, bright emission lines in the spectra of certain nebulae (H II regions), not observed in the laboratory spectra of the same gases, because on Earth the gases cannot be rarefied sufficiently. The term forbidden is misleading; a more accurate description would be “highly improbable.” The emissions result from electrons in long-lived orbits within the radiating atoms—i.e., the transition from an upper energy level to a lower energy level that produces the emissions requires a long time to take place. As a result, emission lines corresponding to such atomic transitions are extremely weak compared with other lines. In the laboratory, moreover, an excited atom tends to strike another particle or the walls of the gas container before it emits a photon, thereby further reducing the possibility of observation. In an H II region in interstellar space, by contrast, the atom will remain undisturbed long enough to emit the photon. Another factor favouring forbidden radiation in an H II region is the transparency of the constituent ionized gases to visible light, which permits the photons given off through the entire depth of the nebula to contribute to the emission lines. See also nebulium.
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planetary nebula: Forms and structure…and the bright, collisionally excited forbidden lines and faint recombination lines of other ions. (Recombination is the process in which an atom at a high stage of excitation captures a lower energy electron and then drops into a lower stage of excitation.) The central stars show a much greater range…
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planetary nebula: Chemical composition…opposed to those determined from collisionally excited lines, but in a much more severe form. There are some nebulae for which the two methods give the same abundances. However, the most extreme discrepancies are factors of 30 or more in the oxygen abundances. Perhaps this wild variation in planetary nebulae…