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Organic And Biological Chemistry

7th Edition
STOKER + 1 other
Publisher: Cengage Learning,
ISBN: 9781305081079

Solutions

Chapter
Section
Chapter 4, Problem 4.70EP
Textbook Problem
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How many hydrogen bonds can form between an acetone molecule and

  1. a. other acetone molecules
  2. b. water molecules

(a)

Interpretation Introduction
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Interpretation:

The maximum number of hydrogen bonds that can form between an acetone molecule and other acetone molecules has to be determined.

Concept Introduction:

Ketone is an organic compound that has carbonyl carbon bonded to two carbon atoms as its functional group.  Carbonyl group is the nonpolar group.

Due to the lone pair of electrons that is present on the oxygen in carbonyl group, hydrogen bonding is possible with water molecules and not with ketone molecules.  Hydrogen bonds are weak force of attraction.

Explanation of Solution

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Acetone has a carbonyl group as its functional group.  Acetone molecule contains a single oxygen atom with two lone pair of electrons on it.  These two lone pairs present on oxygen atom in carbonyl group cannot involve in hydrogen bonding with other acetone molecules...

(b)

Interpretation Introduction

Interpretation:

The maximum number of hydrogen bonds that can form between an acetone molecule and water molecules has to be determined.

Concept Introduction:

Ketone is an organic compound that has carbonyl carbon bonded to two carbon atoms as its functional group.  Carbonyl group is the nonpolar group.

Due to the lone pair of electrons that is present on the oxygen in carbonyl group, hydrogen bonding is possible with water molecules and not with ketone molecules.  Hydrogen bonds are weak force of attraction.

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