Anonymous
Anonymous asked in Science & MathematicsChemistry · 1 decade ago

How to calculate lattice energy of magnesium sulfide?

Mg(s) → Mg(g) ΔH° = 148 kJ/mol

Mg(g) → Mg2+(g) + 2e- ΔH° = 2186 kJ/mol

S8(s) → 8S(g) ΔH° = 2232 kJ/mol

S(g) + 2e- → S2-(g) ΔH° = 450 kJ/mol

8Mg(s) + S8(s) → 8MgS(s) ΔH°f = -2744 kJ/mol

Mg2+(g) + S2-(g) → MgS(s) ΔH°MgS = ?

I'm having trouble because it is 8 moles instead of 1.

Thanks for the help!

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2 Answers

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  • 1 decade ago
    Favorite Answer

    Take the second equation and flip it around. This changes the sign of ΔH°

    Mg2+(g) + 2e- → Mg(g) ΔH°=-2186 KJ/mol

    flip the fourth equation around. Again only the sign of ΔH° changes

    S2-(g) → S(g) + 2e- ΔH°=-450 KJ/mol

    Divide the fifth equation by 8. This also divides the value of ΔH° by 8

    Mg(s) + 1/8S8(s) → MgS(s) ΔH°=-343 KJ/mol

    flip the first equation

    Mg(g) → Mg(s) ΔH°=-148 KJ/mol

    flip the third equation and divide by 8

    S(g) → 1/8S8(s) ΔH°=-279 KJ/mol

    Now combine all the equations and you should get the desired equation. Add all the values for ΔH° and you get the lattice energy for MgS.

    Mg2+(g) + S2-(g) → MgS(s) ΔH°MgS=-3406 KJ/mol

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  • Erika
    Lv 4
    3 years ago

    Lattice Energy Of Magnesium Sulfide

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