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What is the formal charge on phosphorus in a Lewis structure for the phosphate ion that satisfies the octet rule ?

Posted Sep 29 2019

Answered on

The PO4 3-ion Lewis dot structure can be expressed in two ways.

In first way the P atom is doubly bonded to one of the O atoms and singly bonded to other 3 atoms. This lewis dot structure clearly does not comply with the octet rule as it will have 10 electrons in the valence shell of P. The formal charge on P would be 0 for this structure. Formal charge on doubly bonded O would be 0 and 3 singly bonded O's would be -1.

The other structure would be a single bond of P to all 4 O atoms. That structure would satisfy the octet. For this case the formal charge on P would be +1 and all the 4 O atoms would be -1. So the answer would be +1.


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Answered
18 Feb 2019

Will NH4F be acidic, basic or neutral in water?

GIven: pKb NH3=4.75. KaHF=6.6*10^-4.

I found for NH4F to be acidic by finding Ka (NH3) being greater than Kb (HF).

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Intermolecular Forces and Physical Properties of Pure Substances


Which has the highest normal freezing point?
O2
N2
H2
NH3
Which has the lowest enthalpy of fusion?
H2O
Li2O
HCl
HF
Which has the least heat of vaporization?
H2Te
Xe
H2Se
H2O
Which has the highest normal boiling point?
C2H6
NH3
Li2O
CH4
Which has the smallest vapour pressure at 25°C?
O3
SiO2
CO2
H2O

Answered
24 Jun 2019