What Happens When You Add Ammonium Nitrate to Water?

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You may associate ammonium nitrate with explosives; it's commonly used in safety explosives and pyrotechnics as well as fertilizer. But not all ammonium nitrate experiments end with a bang. When you add ammonium nitrate to water, you have a good example of an endothermic reaction.

TL;DR (Too Long; Didn't Read)

Adding ammonium nitrate to water turns the mixture cold and is a good example of an endothermic chemical reaction.

Ammonium Nitrate Properties

The chemical compound ammonium nitrate, a salt of ammonia and ammonium and nitric acid, is a colorless, crystalline solid that is highly soluble in water. Its chemical formula is NH4NO3, meaning it is a molecule made up of atoms of nitrogen, hydrogen and oxygen.

Adding Ammonium Nitrate to Water

Ammonium nitrate consists of ionic bonds packed tightly together. When it comes into contact with water, the polar water molecules interfere with those ions and eventually make them disperse. It takes energy to do this, which is absorbed from the surroundings and makes the solution cold. While some heat is produced when the ammonium nitrate ions interact with the water molecules (i.e., an exothermic reaction), it is a lot less than what is needed for the water molecules to disperse the strong ionic bonds of the ammonium nitrate, so the overall process is an endothermic reaction, or one that absorbs energy from its surroundings. It's for this reason that solid ammonium nitrate is used in commercial cold packs, which are really just a mixture of ammonium nitrate and water. If you hurt yourself, you can mix the contents of the bag together and place it on the injured part of your body. The endothermic reaction of the mixture of ammonium nitrate and water removes heat from the part of the body, "freezing" the painful area.

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Heating Dissolved Ammonium Nitrate

If you gently heat ammonium nitrate that has dissolved in water, the solution breaks down to release nitrous oxide, commonly called laughing gas. Known as thermal decomposition, when the solution decomposes into nitrous oxide and water vapor, this process requires a temperature of between 180 degrees Celsius (356 degrees Fahrenheit) to 250 degrees Celsius (482 degrees Fahrenheit). This should only be done under controlled, supervised conditions in a chemistry lab because ammonium nitrate can cause asphyxiation if too much of it is inhaled, and it can explode at high temperatures. Because solid ammonium nitrate can undergo explosive decomposition when heated in a confined space, its shipment and storage are subject to government regulations.

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Claire is a writer and editor with 18 years' experience. She writes about science and health for a range of digital publications, including Reader's Digest, HealthCentral, Vice and Zocdoc.

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How to Make a Supersaturated Solution of Copper-Sulfate

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A supersaturated solution contains more of the solute than could normally dissolve in solution. You can create this type of solution by adding solute to heated water, which allows the solution to hold more than normal. As this supersaturated solution cools, the excess solute will remain dissolved until a disturbance, such as the addition of more solute. You can create a supersaturated solution of copper(II) sulfate in this way.

    Put on your rubber gloves and safety goggles.

    Fill the beaker with distilled water. Leave some room at the top so that the solution will not overflow during stirring.

    Heat the beaker of water on the hot plate. Any increase in temperature will increase the amount of copper(II) sulfate you can add to the solution. At 100 degrees Celsius, the solubility of copper(II) sulfate is 736 grams per kilogram of water. You needn't heat the water this much; anywhere near the boiling point will be sufficient.

    Monitor the temperature of the water with the thermometer. Stop heating the water once it nears the boiling point of 100 degrees Celsius.

    Add copper(II) sulfate and stir until the heated solution is saturated. When the solution is saturated, copper(II) sulfate will not dissolve anymore.

    Let the solution cool. Once the solution has cooled, it will be a supersaturated copper(II) sulfate solution. Make sure that no particles get into the solution while it cools, which could trigger precipitation of the excess copper(II) sulfate.

    Add solid copper(II) sulfate to the supersaturated solution or let the solution evaporate if you wish to trigger crystallization.

    Warnings

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Serm Murmson is a writer, thinker, musician and many other things. He has a bachelor's degree in anthropology from the University of Chicago. His concerns include such things as categories, language, descriptions, representation, criticism and labor. He has been writing professionally since 2008.

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