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    Electrochimica Acta

    Volume 45, Issues 1–2, 30 September 1999, Pages 351–367

    Cover image

    Magnesium insertion electrodes for rechargeable nonaqueous batteries — a competitive alternative to lithium?

    • Petr NovákCorresponding author contact information, E-mail the corresponding author,
    • Roman Imhof1,
    • Otto Haas
    • Paul Scherrer Institute, Electrochemistry Section, CH-5232 Villigen PSI, Switzerland
    Received 7 February 1999
    Revised 12 March 1999
    Available online 19 October 1999
    • http://dx.doi.org/10.1016/S0013-4686(99)00216-9, How to Cite or Link Using DOI

    Abstract

    Magnesium-based rechargeable batteries might be an interesting future alternative to lithium-based batteries. Here the available results of research, both on rechargeable negative electrodes based either on metallic magnesium or alternative materials, and on materials suitable as positive, magnesium-inserting (counter)electrodes for secondary magnesium batteries, are critically reviewed. The reversible magnesium-metal electrode was scarcely investigated and remains poorly understood. More data are available on host materials capable of reversible magnesium insertion, which are compared with lithium-inserting materials.

    Keywords

    • Rechargeable magnesium batteries;
    • Magnesium metal;
    • Magnesium insertion;
    • Lithium insertion;
    • Insertion electrodes;
    • Nonaqueous magnesium electrolytes;
    • Review

    Figures and tables from this article:

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    Fig. 1. Typical potential regions for the insertion of Li+ and Mg2+ ions into various hosts.

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    Fig. 2. The crystal structure of V2O5.

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    Fig. 3. A cyclic voltammogram of V2O5 in the electrolyte 1 M Mg(ClO4)2+1 M H2O in acetonitrile [56].

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    Fig. 4. A cyclic voltammogram (30th cycle) of Mg(V3O8)2 in the electrolyte MgCl2+AlCl3+EMIC at 80°C [95].

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    Fig. 5. The crystal structure of MoO3.

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    Fig. 6. Cyclic voltammograms of MoO3 in the electrolyte 1 M Mg(ClO4)2+1.5 M H2O in acetonitrile [109]; (—) first cycle, (…) fifth cycle.

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